Mutat Res 257(3):229-306. Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). A U.S. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development. Propylene Glycol: Propylene Glycol is used as a solvent for intravenous, oral, and topical pharmaceutical preparations. CAS Number. Serum levels in poisoning cases have ranged from 0.005 to 432 mg/L. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. In pesticide products, DEGBE acts as an inert ingredient as a deactivator for formulation before the crop emerges from the soil and as a stabilizer. Glycol Ethers. : E181-4 Synonyms Oxitol acetate; 2-Ethoxyethyl acetate; Cellosolve acetate Recommended Use Laboratory chemicals. Ethylene glycol is chemically broken down in the body into toxic compounds. farblose Flüssigkeit mit schwach etherischem Geruch[1]. It is a butyl ether of ethylene glycol. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7]. They react with oxoacids and carboxylic acids to form esters plus water. TEGBE. Reproductive hazard This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Alternative Name. Buy Glycol Ether For $35 | Buy In Bulk Online For $60 | Butyl Cellosolve | Solvent, Coupling Agent & Cleaner | Formula C6H14O2 | Glycol Ether EB SDS | CAS # 111-76-2 | Ethylene Glycol Monobutyl Ether | 2-Butoxyethanol | Ethylene Glycol Monobutyl Ether Acetate | Butoxyethyl Acetate | Butyl Glycol Acetate | Ethylene Glycol Butyl Ether Acetate This original list included 189 pollutants. Contact Us to ask a question, provide feedback, or report a problem. [6], Die Jahresproduktion in Europa betrug 2003 etwa 161.000 Tonnen. Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. Colorless liquid with a mild odor. Toxicological Review of Ethylene Glycol Monobutyl Ether (EGBE) (CAS No. ethylene glycol monobutyl ether (butyl cellosolve) 2909.43.00 101 Ethers, ether-alcohols, ether-phenols, ether-alcohol-phenols, alcohol peroxides, ether peroxides, ketone peroxides (whether or not chemically defined), and their halogenated, sulphonated, nitrated or nitrosated derivatives. Polymers are excluded from the glycol category. [1] Außerdem wird es als Gleitmittel beim Hydraulic Fracturing[10][11] oder als Lösungsmittel beim Aufwältigen von Erdölförderbohrungen verwendet. Diethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ethers. Formula. as part of that chemical's infrastructure. It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". Note that this list is not exhaustive. Conclusion. Return to footnote 13 referrer. EC … Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Uses advised against No Information available Details of the supplier of the safety data sheet COMPANY IDENTIFICATION Supplier: Pon Pure Chemicals Group CHENNAI, TAMILNADU, INDIA 24 Hour Health Emergency (91) … Health Hazard Summary: Overexposure to glycol ethers can cause anemia (a shortage of red blood cells), intoxication similar to the effects of alcohol, and irritation of the eyes, nose, or skin. C 4 H 9 O(CH 2 CH 2 O) 3 H. C 4 H 9 O(CH 2 CH 2 O) n H, n=3-5. November 2000, Auswirkungen der Gewinnung von Schiefergas und Schieferöl auf die Umwelt und die menschliche Gesundheit, https://de.wikipedia.org/w/index.php?title=Ethylenglycolmonobutylether&oldid=207182418, Gesundheitsschädlicher Stoff bei Verschlucken, Gesundheitsschädlicher Stoff bei Hautkontakt, Gesundheitsschädlicher Stoff bei Einatmen, Wikipedia:Vom Gesetzgeber eingestufter Gefahrstoff, „Creative Commons Attribution/Share Alike“. Agent Name. [1] Sie reagiert mit Luftsauerstoff langsam zu Peroxiden. Ethylenglycolmonobutylether kann aus Ethylenoxid und n-Butanol gewonnen werden. 143-22-6. [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. Ethanol and fomepizole may be effective. CAS Number. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Oxidizing agents convert alcohols to aldehydes or ketones. 2-Butyloxyethanol also caused loss of sterols from … Synonym: 1-Acetoxy-2-ethoxyethane, Cellosolve ® acetate, Ethylene glycol monoethyl ether acetate Linear Formula: CH 3 COOCH 2 CH 2 OC 2 H 5 Molecular Weight: 132.16 … It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. 111-76-2) from the group of glycol ethers. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. 4 - Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 ºC. Health issue . Hobson, D. W. et al (1986) A subchronic dermal exposure study of diethylene glycol monomethyl ether and ethylene glycol monomethyl ether in the male guinea pig. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Ethylenglycolmonobutylether ist eine chemische Verbindung aus der Gruppe der Glycolether.                R' = R, H, or groups which, when removed, yield glycol ethers with the structure: R-(OCH2CH)n-OH.                R = alkyl or aryl groups Alcohols exhibit both … The ether being relatively unreactive. Solvents. They react with oxoacids and carboxylic acids to form esters plus water. NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) An official website of the United States government. The level of exposure depends upon the dose, duration, and work being done. Production Industrial routes. AGENCY: Environmental Protection Agency (EPA). C10-H22-O4. The ether being relatively unreactive.                n = 1, 2, or 3; Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. 3 Retain H302 H315 H319 Remove H312 Modify H331 Add GHS06 Dgr Remove GHS07 Wng Retain H302 H315 H319 Modify H331 Add inhalation: ATE = 3 mg/L oral: ATE = 1200 mg/kg bw Resulting Annex VI entry if agreed by COM tration. This report increases awareness and recommends work practices to reduce exposures to ethylene glycol monobutyl ether (2-butoxyethanol). What are its effects? Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH 2 OH) 2. ETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. Ethylene glycol is odorless; odor does not provide any warning of … ACTION: Final rule. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No.                R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; Solvents. 2010. C8-H18-O3. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. : 111-76-2 Formula : C6H14O2 Synonyms : 2-butoxyethanol / BGE / butyl cellosolve / butyl OXITOL / butylglycol / butylglycol ether / EGBE / ethanol, 2-butoxy- / ethyleenglycolmonobutylether / ethylene glycol monobutyl ether / glycolmonobutylether / monobutyl ether of ethyleneglycol 1.2. Ethylene glycol and propylene glycol are organic compounds. Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OH. Surfactant alcohol ethoxylates and their derivatives - removed from the list of hazardous air pollutants in August 2000 - Federal Register – August 2, 2000 (65 FR 47342). Major Category. 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Mention of ethylene glycol monobutyl ether is also in order because of its extensive use in industry. U.S. Environmental Protection Agency. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. EPA/635/R-08/006F. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. Instability 0: Normally stable, even under fire conditions. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Ingestion of sufficient amounts can be fatal. ... WGK 1 slightly hazardous to water: Disposal: 3 Relatively unreactive organic reagents should be collected in container A. Januar 2021 um 17:42 Uhr bearbeitet. 112-34-5. 1-bromopropane – On June 18, 2020, EPA finalized its decision to grant petitions to add 1-bromopropane (1-BP), also known as n-propyl bromide (nPB), to the list of hazardous air pollutants. It is used as a solvent and is found in paint strippers, thinners, and household cleaners. When aerosolized it acts as a disinfectant. Considerable potassium efflux, protein leakage, and inhibition of endogenous respiration were observed in the presence of the more toxic compounds. : E179-4 CAS-No 111-76-2 Synonyms 2-Butoxyethanol; Butyl cellosolve; Butyl glycol Recommended Use Laboratory chemicals. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. Etwa 60 % der Verbindung wird in Europa für Farben und Lacken verwendet, etwa 11 % wird in Wasch- und Reinigungsmitteln verwendet und bis zu 0,5 % wird als Lösungsmittel in Haarfärbemitteln benutzt. They react with oxoacids and carboxylic acids to form esters plus water. Substance name : Glycol Ether EB CAS-No. Ethylene glycol is chemically broken down in the body into toxic compounds. This document evaluates ethylene glycol (EG), diethylene glycol (DG), diethylene glycol monomethyl ether (DGME), diethylene glycol monoethyl ether (DGEE), and diethylene glycol monobutyl ether (DGBE), pesticide inert ingredients for which an exemption from the requirement of a tolerance exists. " DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content. Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. In postnatal studies, there were no significant effects on pup growth or survival at maternally toxic dose levels. Ashby, J; Tennant, RW. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. Formula. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). (See Modification). Ethylene glycol monobutyl ether: Toxic effects include lethargy, coma, anion gap metabolic acidosis, hyperchloremia, hypotension, respiratory depression, hemolysis, renal and hepatic dysfunction. Several studies of rodents exposed orally or by inhalation showed ethylene glycol to be fetotoxic. Data from animal studies have been examined from the standpoint of dose-response relationships and the sensitivity of various animal species, including man, to the effects of this chemical. Abbreviations for 2-butoxyethanol include EGBE and BE [1]. 111-76-2. Fundamental & Applied Toxicology 6:2:339-348. 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. Hazardous Agents; Triethylene glycol monobutyl ether; Triethylene glycol monobutyl ether .                n = 1, 2, or 3 The relevance of this finding to humans is uncertain. In rats, deaths in response to single oral exposures are attributable to narcosis, whereas delayed deaths result from lung congestion and renal failure. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Workers may be harmed from exposure to 2-butoxyethanol. Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). Ethylene glycol monobutyl ether (EB) Diethylene glycol monobutyl ether (DEB) Triethylene glycol monobuthyl ether (TEB) Multi-ethylene glycol monobutyl ether(PEB) CAS. The ether being relatively unreactive. 2 BUTOXYETHANOL BUTYL GLYCOL ETHYLENE GLYCOL BUTYL ETHER Technical grade 2-Butoxyethanol is an organic solvent which is a clear, colourless liquid with an ether-like odour. In a biphasic kerosene-water system, 3-methoxybutanol, 2-butyloxyethanol, and diethylene glycol monobutyl ether were again found to be more toxic than ethylene glycol monomethyl ether. In laboratory animals, low-level exposure to certain glycol ethers can cause birth … For example KCN or Ca(CN)2, 2 - Includes mono- and di- ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n -OR' where [7], Die Dämpfe von Ethylenglycolmonobutylether können mit Luft bei erhöhter Temperatur ein explosionsfähiges Gemisch (Flammpunkt 61 °C, Zündtemperatur 240 °C) bilden. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. (1991) Definitive relationships among chemical structure, carcinogenicity and mutagenicity for 301 chemicals tested by the U.S. NTP. On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. 7412(b)(1)) to read as follows: 2 - Includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR' , where: It is liable to form peroxides on exposure to air and light. Triethylene glycol monobutyl ether. MDL number MFCD00002881. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). C 4 H 9 OCH 2 CH 2 OCH 2 CH 2 OH. It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. 2 Eye Irrit. It attacks some forms of plastics, rubber and … Molecular Weight 162.23 . Since 1990, EPA has modified the list through rulemaking to include 187 hazardous air pollutants. C 4 H 9 OCH 2 CH 2 OH. 12. Diethylene glycol monobutyl ether. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. DEG is used as a component of multiple different products including antifreeze preparations, cosmetics, lubricants, brake fluids, wallpaper strippers, heating/cooling fuel and as a plasticizer. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. 7412(b)(1). 111-76-2 - POAOYUHQDCAZBD-UHFFFAOYSA-N - Ethylene glycol mono-n-butyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. Learn more. Diese Seite wurde zuletzt am 2. [1] In kommerziellen Produkten werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken. It is an odorless, colorless, sweet-tasting, viscous liquid. EU -Scientific Committee on Consumer Products: Nachrichten aus der Chemie, 60, Januar 2012, S. 31–34. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. They react with oxoacids and carboxylic acids to form esters plus water. It can harm the eyes, skin, kidneys, and blood. Synonyms. The ether being relatively unreactive. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. Appearance. Agent Name. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). 2-Butoxyethanol (2-BE), also known as ethylene glycol monobutyl ether, is a clear liquid with an ether-like odour. It is an ether-ester derivative. Project No. Maternally toxic dose levels of ethylene glycol monobutyl ether and ethanol were associated with increased embryo lethality in teratology probe studies. Colorless and clear liquid. 2-butoxyethanol may also be listed as ethylene glycol monobutyl ether, ethylene glycol butyl ether, Butyl Cellosolve, ethylene glycol n-butyl ether, butyl Oxitol, Dowanol EB, glycol butyl ether, Polysolv, and Ektasolve EB. (1993d) Ethylene glycol monobutyl ether: acute dermal toxicity test in the rabbit. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. They are alcoholic compounds due to the presence of –OH groups. Which products contain ethylene glycol? Ingestion of sufficient amounts can be fatal. List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . [7], Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. The EU Ecolabel may not be awarded to substances or mixtures classified as such. Major Category. 13/606, Safepharm Laboratories, Ltd., Derby, U.K. Report to Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan. Hydrogen Sulfide – added to the list inadvertently but removed by Congress with Presidential approval in 1991. [6], Ethylenglycolmonobutylether ist eine farblose Flüssigkeit mit schwach etherischem Geruch. low . Floats and mixes slowly with water. Hazardous Agents; By Types Of Agents; Solvents ; Glycol Ethers (E Series) Diethylene glycol monobutyl ether; Diethylene glycol monobutyl ether. Where is it found and how is it used? Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. Ethylene glycol monobutyl ether for synthesis. 3 - Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less. The available information on the acute and subchronic toxicity of ethylene glycol monobutyl ether is reviewed. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). Harm to the fetus occurs only at exposure levels that harm the pregnant animal. [9] Ethylene glycol has a sweet taste and is often accidentally or intentionally ingested. These criteria include recommendations for preventing … On November 29, 2004 (69FR69320) this proposal was made final. Alternative Name. 112-34-5. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of … [1] Die Verbindung hat eine geringe akute Toxizität. In both the ethylene and diethylene glycol series, the relative rate of absorption declined from methyl to ethyl to butyl ether derivatives. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. 5 - A type of atom which spontaneously undergoes radioactive decay. [7] Damit zählt es zu den chemischen Substanzen, die in großen Mengen hergestellt werden („High Production Volume Chemical“, HPVC) und für die von der Organisation für wirtschaftliche Zusammenarbeit und Entwicklung (OECD) eine Datensammlung zu möglichen Gefahren („Screening Information Dataset“, SIDS) angefertigt wurde. First affect the central nervous system ( CNS ), then the heart, inhibition... The heart, and inhibition of endogenous respiration were observed in the into..., skin, kidneys, and strong reducing agents Name ethylene glycol N-BUTYL ether may with! Include recommendations for preventing … ethylene glycol monobutyl ether has been shown to cause harm to fetus! Form esters plus water with the following: Oxidizers ( NIOSH, 2016 ), Glycolmonoalkylether verhalten sich is ethylene glycol monobutyl ether hazardous! Niosh, 2016 ) of this finding to humans is uncertain list inadvertently but removed by Congress with Presidential in. 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